Engineering
Chemistry
Optical Isomerism
Empirical and Molecular Formula
Question

(+) Tartaric acid has a specific rotation of +15°. The specific rotation of a mixture of 70% (+) Tartaric acid & 30% (–) Tartaric acid is

10.5°

4.5°

7.5 °

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Solution
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Optical  purity=QmQp×100  or  |d|d+×100
O.P.=|0.700.30|1×100=40%
Qm15°×100=40
Qm = 6°