Engineering
Chemistry
Chemical reactions of phenol
Question

            
Which is/are true for above reaction

Total eight organic  products can be produced in significant amount    

AlCl3 must be anhydrous

It is known as Fries rearrangement

it follows only intramolecular mechanism

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Solution

The reaction shown is the Fries rearrangement, where phenolic esters rearrange to ortho- and para-hydroxy ketones using a Lewis acid catalyst like anhydrous AlCl₃. It is an intramolecular rearrangement, meaning the acyl group migrates within the same molecule. Anhydrous AlCl₃ is crucial to avoid hydrolysis of the acyl chloride. For a disubstituted benzene like this, multiple products (ortho and para to each OH) are possible, but the total number is not eight.

Final answer: The true statements are "AlCl3 must be anhydrous" and "It is known as Fries rearrangement".