Engineering
Chemistry
Mercury Tube Piston and SPM
Question

A closed tank has two compartments A and B, both filled with oxygen (assumed to be ideal gas). The partition separating the two compartments is fixed and is a perfect heat insulator (Figure 1). If the old partition is replaced by a new partition which can slide and conduct heat but does NOT allow the gas to leak across (Figure 2), the volume (in m3) of the compartment A after the system attains equilibrium is ____.

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Solution

P and T will be same in both compartment

V1V2=n1n2=P1V1T1P2V2T2=5×1400×3003×1=54

 VA = 59× 4 = 209= 2.22