Engineering
Chemistry
Application of Radioactivity
Question

A closed vessel with rigid walls contains 1 mol of  92238U and 1 mol of air at 298 K. Considering complete decay of  92238U  to 82206Pb, the ratio of the final pressure to the initial pressure of the system at 298K is

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Solution

In conversion of 92238U  to82206Pb, 8 α - particles and 6 β particles are ejected.

The number of gaseous moles initially = 1 mol

The number of gaseous moles finally = 1 + 8 mol; (1 mol from air and 8 mol of 2He4)

So the ratio = 9/1 = 9