Engineering
Chemistry
Chemical Reaction of Aldehyde and Ketones
Question

A compound that gives a positive iodoform test is

3-pentanone

3-pentanol

1-pentanol

2-pentanone

JEE Advance
College PredictorLive

Know your College Admission Chances Based on your Rank/Percentile, Category and Home State.

Get your JEE Main Personalised Report with Top Predicted Colleges in JoSA

Solution

The iodoform test detects methyl ketones (R-CO-CH3) or alcohols that can be oxidized to methyl ketones (like CH3CH(OH)R).

Let's analyze the options:

• 3-pentanone: CH3CH2COCH2CH3 (not a methyl ketone)

• 3-pentanol: CH3CH2CH(OH)CH2CH3 (oxidizes to 3-pentanone, not methyl ketone)

• 1-pentanol: CH3(CH2)3CH2OH (oxidizes to aldehyde, not ketone)

• 2-pentanone: CH3COCH2CH2CH3 (methyl ketone - positive test)

Final answer: 2-pentanone