Engineering
Chemistry
Classification of Alcohol
Question

 A compound with molecular formula C6H14O4 does not give litmus test and does not give colour with 2,4–DNP. It reacts with excess MeCOCl to give a compound whose vapour density is 117. Compound A contains how many hydroxy groups?

1

2

4

3

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Solution
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C6H14O4 MeCOCl Mwt = 234
Mwt = 150
Mwt = 234-150 = 84 = 2×(42)
           
Hence 2 OH groups are present.

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