Engineering
Chemistry
Back Bonding and Electron deficient Bonding
Question

Among the following, the correct statement(s) is(are)

Al(CH3)3 has the three-centre two-electron bonds in its dimeric structure.

The Lewis acidity of BCl3 is greater than that of AlCl3.

AlCl3 has the three-centre two-electron bonds in its dimeric structure.

BH3 has the three-centre two-electron bonds in its dimeric structure.

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Solution

2Al(CH3)3 →dimer Al2(CH3)6

  

2 AlCl3 →dimer Al2Cl6

2 BH3 →dimer B2H6

Lewis acidic character

Due to more electronegativity of B it has more lewis acidic character.