Engineering
Chemistry
VSEPR Theory
Hybridisation
Question

Among the triatomic molecules / ions, BeCl2, N3, N2O, NO2+, O3, SCl2, ICl2, I3 and XeF2 the total number of linear molecule(s) / ion(s) where the hybridization of the central atom does not have contribution form the d-orbital(s) is:

[Atomic number: S = 16, Cl = 17, I = 53 and Xe = 54]

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Solution

 BeCl2,N3,N2O,NO2+,O3,SCl2,ICl2,I3,XeF2

BeCl2 → sp → linear

N3splinear

N2O → sp → linear

NO2splinear

O3 → sp2 → bent

SCl2 → sp3 → bent

I3sp3dlinear

ICl2sp3dlinear

XeF2 → sp3d → linear

So among the following only four (4) has linear shape and no d-orbital is involved in hybridization