Engineering
Physics
Surface Tension and Surface Energy
Question

Consider a liquid contained in a vessel. The liquid-solid adhesive force is very weak compared to the cohesive force in the liquid. The shape of the liquid surface near the solid (as seen from air) shall be

convex

horizontal

concave

almost vertical

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Solution
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When liquid-solid adhesive forces are weaker than liquid cohesive forces, the liquid molecules are more attracted to each other than to the solid surface. This causes the liquid to minimize its contact with the solid. The surface curves outward, forming a convex meniscus. This is mathematically described by a positive contact angle θ > 90° in Young's equation: γsa-γsl=γlacosθ, where weak adhesion results in a large θ.

Final answer: convex