Engineering
Chemistry
Carboxylic Acids
Aromaticity
Acidic and Basic Oxides
Question

Consider following compounds.

(a)  Number of compounds which are aromatic (x).
(b)  Number of compounds which can evolve H2 gas on reaction with Na metal (y).
#(c)  Number of compounds which can evolve CO2 gas on reaction with NaHCO3 (z). 
[If answer is x,y & z respectively, then fill 0xyz in sheet]

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Solution
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Aromatic compounds follow Hückel's rule (4n+2 π-electrons in a cyclic conjugated system). Compounds with -OH or -COOH groups can evolve H2 with Na metal, while only carboxylic acids (-COOH) evolve CO2 with NaHCO3.

Analyzing the structures: (I) is aromatic (6π), (II) non-aromatic, (III) aromatic (6π), (IV) aromatic (6π), (V) non-aromatic. So x=3. For H2 with Na: (I) phenol, (III) carboxylic acid, (IV) alcohol, (V) carboxylic acid → y=4. For CO2 with NaHCO3: only carboxylic acids (III) and (V) → z=2.

Final answer: 0342