Engineering
Chemistry
Inductive Effect
Basic Concepts of GOC
Basic concepts of organic chemistry
Question

Consider following groups and write number of groups which have –I effect

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Solution
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The –I effect (negative inductive effect) occurs when a group withdraws electron density through sigma bonds. Groups with high electronegativity or a positive charge exhibit this effect.

Analyzing the given groups:

CH3 (methyl) is electron-donating (+I).

CH2Cl (chloromethyl) is electron-withdrawing (–I) due to the Cl atom.

(CH3)+ (carbocation) is strongly electron-withdrawing (–I) due to the positive charge.

CH2CH3 (ethyl) is electron-donating (+I).

Therefore, only two groups have the –I effect.

Final Answer: 2