Engineering
Chemistry
Integrated Rate Law
Order of Reaction and Law of Mass Action
Question

Consider the reaction :
A →  B + C 
Initial concentration of A is 1 M. 20 minutes time is required for completion of 20 % reaction. 
If d[B]dt= k[A],  then half life (t1/2) is 

None of these

55.44 min.

62.13 min

50 min

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Solution

k=1t.lnC0C⇒0.693t1/2=120.ln10.8

t1/2 = 62.13 min.