Foundation
Chemistry Foundation
Electron Gain Enthalpy or Electron Affinity
Question

Electron affinity of X would be equal to -

none of these.

ionisation potential of X.

electron affinity of X.

ionisation potential of X.

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Solution

Electron affinity (EA) is the energy change when an atom gains an electron: X + e⁻ → X⁻. The ionization potential (IP) is the energy to remove an electron: X → X⁺ + e⁻.

For the negative ion X⁻, its ionization potential is the energy for X⁻ → X + e⁻. This is the reverse of the electron affinity reaction for X. Therefore, the ionization potential of X⁻ is equal to the negative of the electron affinity of X.

Mathematically: IP(X)=EA(X)

Final Answer: ionization potential of X⁻.