Engineering
Chemistry
Entropy Calculations
Question

For the process

 H2O (ℓ) → H2O (g)

at t = 100°C and 1 atmosphere pressure, the correct choice is

ΔSsystem  > 0 and ΔSsurroundings < 0

ΔSsystem  < 0 and ΔSsurroundings < 0

ΔSsystem  < 0 and ΔSsurroundings > 0

ΔSsystem  > 0 and ΔSsurroundings > 0

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Solution

H2O(ℓ) → H2O(g)

For system

Liquid is getting converted into gas  ΔSsystem>0

Process is endothermic ⇒ Heat is given by system

ΔSsurrounding =qsurrT

where qsurrounding = –ΔH

      qsurr < 0

           ΔSsurr < 0