Engineering
Chemistry
Large or Small Equilibrium Constant Problems
Question

For the reaction,
NH4HS (s) ⇌ NH3(g) + H2S (g),     KP = 1225 (torr)2
In a vessel, NH3(g) at a partial pressure of 40 torr and H2S(g) at a partial pressure of 25 torr is taken. After a long time, the total pressure of gases in the vessel becomes

70 torr

71.58 torr

less than 65 torr

65 torr

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Solution

No backward reaction, since QP < KP . So pressure remained unchanged.