Engineering
Chemistry
Liquefaction and Critical Temperature Pressure and Volume
Vander Waal Gas and compressibility Factor
Pressure Volume and Temperature
Question

For three different real gases, liquifaction curve is plotted at a temperature T1 Kelvin. Which of the following options is correct on the basis of the graph?

Gas 'A' can be liquified even if temperature is greater than T1 just by increase in pressure.

Gas 'C' can be liquified by application of pressure at a temperature greater than T1.

Critical temperature(TCr) of A, B and C are in the order TCr, C > TCr, B > TCr, A

Gas 'B' can be liquified by application of pressure even at a temperature greater than T1.

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Solution
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The graph shows liquefaction curves for gases A, B, and C at temperature T₁. A gas can be liquefied by pressure only if its temperature is below its critical temperature (TCr). The curve's position indicates TCr; a higher curve means a higher TCr. From the graph, the order is C (highest curve) > B > A (lowest curve). Therefore, at T₁, which is below all their TCr values, all can be liquefied. However, only gas C, with the highest TCr, could potentially be liquefied at a temperature greater than T₁, as its TCr is the highest.

Final Answer: Gas 'C' can be liquified by application of pressure at a temperature greater than T₁.