HClO4 + CH3CN \rightarrow_{}^{} [X]+ + [Y]– NOF + ClF3 \rightarrow_{}^{} [X1]+ + [Y1]– 2ClO3– + SO2 → [X2] + [Y2]–2 2NOCl + Sn \rightarrow_{}^{} [X3] + [Y3] PCl5 + ICl \rightarrow

Linked Question 1

Choose the incorrect options :

A

[Y]^– and [X₄]⁺ have same hybridisation.

B

[X₂] and [X₃] are sp² hybridised

C

[Y]^– and [Y₁]^– both are planar

D

Bond length of [Y₃] is greater than [X₁]⁺

$∵ ∆ H > 0$

$∆$ S > 0 So entropy driven.

Linked Question 2

What is the hybridisation and shape of [Y₁]^– ?

A

sp³d², square pyramidal

B

sp²d, trigonal bipyramidal

C

sp³d², square planar

D

sp³d², octahedral

$∵ ∆ H > 0$

$∆$ S > 0 So entropy driven.

Linked Question 3

Choose the correct option for [X₂] :

A

Bond angle is greater than 120°

B

It is diamagnetic

C

It has bond angle less than NO₂

D

It is sp³ hybridised

$∵ ∆ H > 0$

$∆$ S > 0 So entropy driven.

HClO₄ + CH₃CN → CH₃CNH⁺ + ClO₄^–

NOF + ClF₃ → NO⁺ + ClF₄^–

2ClO₃^– + SO₂ → 2ClO₂ + SO₄^2–

2NOCl + Sn → SnCl₂ + 2NO

PCl₅ + ICl → [PCl₄]⁺ + [ICl₂]^–