Engineering
Chemistry
Preparation of Alkyl Halide
Reactions of Organometallic Compound Grignard Reagents
Question

How many litres of ethene is required to prepare 90 gm of ethane by the following method at STP.
         CH2=CH2HClP1Et2OMgP2HClEtH  (Ethane)

44.8 litres

22.4 litres

6.72 litres

None of these

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Solution

CH2=CH2HClCH3CH2ClEt2OMgCH3CH2MgClHClCH3CH3
Moles of ethane =weightM.weight=9030=3  moles
3 moles ethene will yield 3 moles of ethane
volume of ethene at STP = 3 × 22.4 = 67.2 litre