Engineering
Chemistry
Empirical and Molecular Formula
Chemical Equation and Stoichiometric Calculation
Preparation of Alkyl Halide
Question

How many litres of ethene would be produced when 2.62 gm of vinyl magnesium bromide is treated with 224 ml of ethyne at STP.

0.448 litre

0.08 litre

1.12 litre

0.224 litre

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Solution
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2CH2 = CHMgBr + HC CH 2CH2 = CH2 + BrMg – C C – MgBr
  (2.62131) mole    (22422400) moles
    0.02 mole          0.01 mole
Since, both acidic H of HCCH reacts with CH2=CHMgBr
So, no. of moles of CH2=CH2 produced = 0.02
    Amount in litres = 0.02 × 22400 = 0.448 L