Engineering
Chemistry
Degree of Freedom Heat Capacities

Question

Hybridization was introduced to explain molecular geometry also it predicts, bond parameters like bond angle, bond length, bond order etc. The VSEPR model considers double and triple bonds to have slightly greater repulsive effects than single bonds because of the repulsive effect of π electrons. Multiple bonds, like lone pairs, tend to occupy more space than single bond and to cause distortions that in effect squeeze the rest of the molecule together. In molecules that have both lone pairs and multiple bonds, these features may compete for space.

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Linked Question 1

What will be the hybridisation of nitrogen atom in the structural isomeric form of hyponitrous acid (H2N2O2)?

sp3d, sp3

sp2, sp2

sp3, sp3

sp3, sp2

Solution
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Structural isomer of hyponitrous acid. (H2N2O2) is

(NH2 – NO2) Nitramide

Linked Question 2

Compare the bond angle (O–P–O) in the P3O105– (tripoly phosphate ion).

γ > α > β

γ > β > α

β > α > γ

α > β > γ

Solution
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Verified by Zigyan

Due to repulsion of double bond γ > α > β