Identify the binary mixture(s) that can be separated into individual compounds, by differential extraction, as shown in the given scheme.

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Ph–COOH + NaOH Ph–COONa + H2O ; Ph–CH2OH + NaOH No reaction
Can be separated
Ph–COOH + NaHCO3 Ph–COONa + H2O + CO2 ; Ph–CH2OH + NaHCO3 No reaction
Can be separated
Ph–CH2OH + NaOH No reaction ; Ph–CH2–COOH + NaOH Ph–CH2–COONa + H2O
Can be separated
Ph–CH2OH + NaHCO3 No reaction ;
Ph – CH2COOH + NaHCO3 Ph–CH2COONa + H2O + CO2
Can be separated