Engineering
Chemistry
Distinction tests
Qualitative analysis of organic compounds
Acidic and Basic Oxides
Question

Identify the binary mixture(s) that can be separated into individual compounds, by differential extraction, as shown in the given scheme.

 

C6H5CH2OH and C6H5CH2COOH

C6H5OH and C6H5COOH

C6H5COOH and C6H5CH2OH

C6H5CH2OH and C6H5OH

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Solution

Ph–COOH + NaOH Ph–COONa + H2O   ;            Ph–CH2OH + NaOH No reaction

  Can be separated

Ph–COOH + NaHCO3  Ph–COONa + H2O + CO2 ; Ph–CH2OH + NaHCO3  No reaction

Can be separated

Ph–CH2OH + NaOH  No reaction  ; Ph–CH2–COOH + NaOH Ph–CH2–COONa + H2O

Can be separated

Ph–CH2OH + NaHCO3  No reaction ;

Ph – CH2COOH + NaHCO3  Ph–CH2COONa + H2O + CO2

Can be separated