Engineering
Chemistry
Hydrometallurgy and Leaching
Extraction of Gold Silver Aluminium
Question

In the cyanide extraction process of silver from argentite ore, the oxidizing and reducing agents used are:

HNO3 and Zn dust respectively

O2 and Zn dust respectively

O2 and CO respectively

HNO3 and CO respectively

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Solution

Ag2S + 4NaCN        Na2S + 2Na[Ag(CN)2]

4Na2S + 5O2 (O.A.) + 2H2O   2Na2SO4 + 4NaOH + 2S

2Na[Ag(CN)2]  + Zn (R.A.)  Na2[Zn(CN)4] + 2Ag