Engineering
Chemistry
Preparation of Alkyl Halide
Question

KI in acetone, undergoes SN2 reaction with each of P, Q, R and S. The rates of the reaction vary as

 

R > P > S > Q

S > R > P > Q

P > R > Q > S

P > Q > R > S

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Solution

 

Rate of SN2  α1sterichendrance

                  α δ+ charge on carbon

                  α Stability of transition state

So, S > R > P > Q

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