Engineering
Chemistry
First Law and Various Process
Question

One mole of an ideal gas is taken from a to b along two paths denoted by the solid and the dashed lines as shown in the graph below. If the work done along the solid line path is ws and that along the dotted line path is wd, then the integer closet to the ratio wd / ws is

 

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Solution

For solid line path show approxy isothermal process

∴ work done |WS| = 2.303 (PV) log 5.5.5

=2.303 × 4 × .5 × log 11

 4.79

for dashed line path work done

wd = 4 × |2 – .5| + 1 × |3 – 2| + .5 × |5.5 –3|

= 6 + 1 + 1.25 = 8.25

 wdws=8.254.8=1.712