Select the correct structure for complex tricarbonyl (η4-Cyclobutadienyl) iron(0).
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The complex is tricarbonyl(η4-cyclobutadienyl)iron(0). The η4 hapticity means the cyclobutadienyl ligand is bonded to the iron center using all four of its carbon atoms in a planar, side-on fashion. This bonding mode is characteristic for antiaromatic rings like cyclobutadiene, which form stable complexes with metals. The iron is in the 0 oxidation state. The three carbonyl (CO) ligands are terminal. The correct structure must show the Fe(CO)3 unit coordinated to the flat, square cyclobutadiene ring, not edge-bound or through a single carbon.
Final Answer: The first structure is correct.