Select the incorrect statement(s) from the following:

Engineering

Chemistry

Nucleophilic Substitution

Reactions of Organometallic Compound Grignard Reagents

Aromatic Nucleophilic Substitution

Sulphonation of organic compound

Halogenation of aromatic compounds

Question

Select the incorrect statement(s) from the following:

When HCOOEt is treated with MeMgBr in excess followed by hydrolysis it will results in the formation of tertiary alcohol.

Rate of sulphonation of C₆H₆ & C₆D₆ will be equal

Product. Product is enantiomer of the reactant.

On treatment of salicylic acid with Br₂ / water (in excess) it results in a dibromo product.

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Isotopic effect is observed in sulphonation.
Salicylic acid gives 2,4,6-tri bromo phenol (i.e. decarboxy bromination takes place)
Product is sec. alcohol.
Products are diastereomers