Select the incorrect statement(s) from the following:

Engineering

Chemistry

Nucleophilic Substitution

Reactions of Organometallic Compound Grignard Reagents

Aromatic Nucleophilic Substitution

Sulphonation of organic compound

Halogenation of aromatic compounds

Question

Select the incorrect statement(s) from the following:

On treatment of salicylic acid with Br₂ / water (in excess) it results in a dibromo product.

When HCOOEt is treated with MeMgBr in excess followed by hydrolysis it will results in the formation of tertiary alcohol.

Product. Product is enantiomer of the reactant.

Rate of sulphonation of C₆H₆ & C₆D₆ will be equal

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Isotopic effect is observed in sulphonation.
Salicylic acid gives 2,4,6-tri bromo phenol (i.e. decarboxy bromination takes place)
Product is sec. alcohol.
Products are diastereomers