Engineering
Chemistry
Batteries and Fuel Cell
Question

The anodic half-cell of lead-acid battery is recharged using electricity of 0.05 Faraday. The amount of PbSO4 electrolyzed in g during the process is: (Molar mass of PbSO4 = 303 g mol–1)

22.8

15.2

7.6

11.4

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Solution

Pb(s)+SO42−→PbSO4+2e−

For 2F current passed, PbSO4 deposited = 303 g/mol

For 0.05 F: PbSO4 deposited =0.05×3032=7.6  g