Engineering
Chemistry
Intensive Extensive State and Path Function
Question

The concentration of R in the reaction R  P was measured as a function of time and the following data is obtained:                         

[R] (molar)

1.0

0.75

0.40

0.10

t (min.)

0.0

0.05

0.12

0.18

The order of the reaction is:

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Solution
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R   P

Assume zero order

R = [R0] – kt

 k=[R0][R]t

 k1=10.750.5=5

 k2=10.40.12=5

 k3=10.10.18=5

  order of reaction should be zero.

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