Engineering
Chemistry
Inductive Effect
Basic Concepts of GOC
Acidic and Basic Oxides
Question

The correct decreasing order for acid strength is:

NO2CH2COOH > NCCH2COOH > FCH2COOH > ClCH2COOH

NO2CH2COOH > FCH2COOH > CNCH2COOH > ClCH2COOH

FCH2COOH > NCCH2COOH > NO2CH2COOH > ClCH2COOH

CNCH2COOH > O2NCH2COOH > FCH2COOH > ClCH2COOH

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Solution

Acid strength in this case varies directly with the electron withdrawing power of the groups attached to the a-carbon of CH3COOH. The order of electron withdrawing tendency is

NO2 > CN > F > Cl