Engineering
Chemistry
Dual Behaviour and de Broglie Hypothesis
Question

The de Broglie wavelength (λ) associated with a photoelectron varies with the frequency (ν) of the incident radiation as, [ν0 is threshold frequency]

λ∝1(ν−ν0)12

λ∝1(ν−ν0)

λ∝1(ν−ν0)32

λ∝1(ν−ν0)14

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Solution

λ=hmv

According to Einstein’s theory of photoelectric effect:

hν = hν0 + KE

hν=hνo+12mv2

2h(ν – ν0) = mv2

2h(ν−ν0)m=v2

v∝(ν−νo)12

λ∝hm(ν−νo)12

λ∝1(ν−νo)12