Engineering
Chemistry
Relative Lowering in Vapour Pressure
Question

The degree of dissociation (α) of a weak electrolyte AxBy is related to van't Hoff factor (i) by the expression

α=i-1(x+y-1)

α=x+y+1i-1

α=x+y-1i-1

α=i-1x+y+1

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Solution

AxBy —→ xAy+ + yBx–

1 – α xα yα

i = 1 – α + xα + yα

i = 1 + α(x + y – 1)

 

α=i-1(x+y-1)