Engineering
Chemistry
Entropy Calculations
Question

The entropy change involved in the isothermal reversible expansion of 2 moles of an ideal gas from a volume of 10 dm3 to a volume of 100 dm3 at 27°C is

35.8 J mol–1 K–1

38.3 J mol–1 K–1

32.3 J mol–1 K–1

42.3 J mol–1 K–1

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Solution

ΔS=nRlnV2V1

=2.303nRlogV2V1

=2.303×2×8.314×log10010

=38.3 J mol–1 K–1

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