Engineering
Chemistry
Degree of Freedom Heat Capacities
Question

The first ionisation potential of Na is 5.1 eV. The value of electron gain enthalpy of Na+ will be: 

–10.2 eV

–5.1 eV

–2.55 eV

+2.55 eV

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Solution
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Na(g) + 5.1 eV   Na+(g) + e¯

Ionisation energy of Na =  – Heg of Na+

                                              or

Na   Na+ + e¯            H = 5.1 eV

Na+ + e¯  Na            H = – 5.1 eV

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