Engineering
Chemistry
Crystal Field Theory and Valence Bond Theory
Question

The magnetic moment (spin only) of [NiCl4]2– is :

5.46 BM

2.82 BM

1.41 BM

1.82 BM

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Solution

In the paramagnetic and tetrahedral complex [NiCl4]2–, the nickel is in +2 oxidation state and the ion has the electronic configuration 3d8. The hybridisation scheme is as shown in figure.

μB.M.=n(n+2)=2(2+2)=8=2.82BM