Engineering
Chemistry
Crystal Field Theory and Valence Bond Theory
Colour and Magnetism
Question

The octahedral complex of a metal ion M3+ with four monodentate ligands L1, L2, L3 and L4 absorb wavelengths in the region of red, green, yellow and blue, respectively. The increasing order of ligand strength of the four ligands is:

L4 < L3 < L2 < L1

L1 < L2 < L4 < L3

L3 < L2 < L4 < L1

L1 < L3 < L2 < L4

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Solution

Energydecresingorder

Strength of ligand α energy of light absorbed

=hcλ

L1 < L3 < L2 < L4