Engineering
Chemistry
Acid Base Theories
Question

The pair(s) of coordination complexes/ ions exhibiting the same kind of isomerism is(are)

[Cr(NH3)5Cl]Cl2 and [Cr(NH3)4Cl2]Cl

[Co(NH3)4Cl2]+ and [Pt(NH3)2(H2O)Cl]+

[CoBr2Cl2]2– and [PtBr2Cl2]2–

[Pt(NH3)3(NO3)] Cl and [Pt(NH3)3Cl] Br

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Solution
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(A)        [Cr(NH3)5Cl]Cl2 does not show any isomerism

             [Cr(NH3)4Cl2]Cl show GI.

(B)        [Co(NH3)4Cl2]+ show GI

             [Pt(NH3)2(H2O)Cl]+ show GI 

(C)        [CoBr2Cl2]2– sp3  hybridised does not show any isomerism

             [PtBr2Cl2]2–  dsp2 hybridised show GI

(D)        [Pt(NH3)3(NO3)] Cl show ionisation isomerism

             [Pt(NH3)3Cl] Br show ionisation isomerism                                 

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