Engineering
Chemistry
Entropy Calculations
Question

The ratio of slopes of log P vs log V for reversible adiabatic process and reversible isothermal process of an ideal gas is equal to:

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1 – γ

1γ

γ – 1

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Solution
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PVγ =  constant for adiabatic expansion and

PV = constant for isothermal expansion

∴ log= –γlogV      slope = –γ

log= –logV            slope =–1

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