The reaction of white phosphorus with aqueous NaOH gives phosphine along with another phosphorus containing compound. The reaction type ; the oxidation states of phosphorus in phosphine and the other product are respectively :The reaction of white phosphorus with aqueous NaOH gives phosphine along with another phosphorus containing compound. The reaction type ; the oxidation states of phosphorus in phosphine and the other product are respectively :
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3NaOH + P4 + 3H2O PH3(–3) + 3NaH2PO2(+1)
H2PO2– + 2OH– 2H2 + PO43– (+5)