The real number k for which the equation 2x3 + 3x + k = 0 has two distinct real roots in [0, 1] :
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f (x) = 2x3 + 3x + k
f ' (x) = 6x2 + 3
f ' (x) is always positive, hence f (x) is an increasing function
i.e. f (x) has only one real root.