Engineering
Chemistry
Gibbs Free Energy Entropy and Spontaneity
Question

The standard reaction Gibbs energy for a chemical reaction at an absolute temperature T is given by

ΔrG° = A – BT

Where A and B are non-zero constants. Which of the following is TRUE about this reaction?

Exothermic if A > 0 and B < 0

Endothermic if A < 0 and B > 0

Endothermic if A > 0

Exothermic if B < 0

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Solution

ΔG° = ΔH° – TΔS°

ΔG° = A – BT

In endothermic reaction ΔH = +ve. Hence, A = +ve