Engineering
Chemistry
EMF Calculation and Galvanic Cell
Question

The standard reduction potentials for

Zn2+ / Zn, Ni2+ / Ni, and Fe2+ / Fe are –0.76, –0.23 and 0.44 V respectively. The reaction

X + Y2+  X2+ + Y will be spontaneous when :

X = Ni, Y = Fe   

X = Ni, Y = Zn

X = Zn, Y = Ni

X = Fe, Y = Zn 

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Solution

Y > E°X

Hence, Y = Ni and X = Zn