Engineering
Chemistry
Entropy Calculations
Question

Three moles of an ideal diatomic gas undergoes a change in state from A to B reversibly as follows : Which of the following statements is/are correct regarding the above process :

Work done on the gas is 2700 R.

In the above process, pressure varies inversely with square of volume.

Heat supplied to the gas is 4050 R.

Data insufficient for the calculation of work and heat supplied.

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Solution
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From graph, slope = –1

∴ eq = log10V + log10T = constant

∴ VT = constant or PV2 = constant

C=Cv+R1-nC=5R2+R1-2=3R2

q=nCΔT=3×3R2×(1000-100)=4050R

ΔU=nCvΔT=3×5R2×(1000-100)=6750R

∴ W = ΔU – q = 6750 R – 4050 R = 2700 R

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