Question

Upon heating KClO₃ in the presence of catalytic amount of MnO₂, a gas W is formed. Excess amount of W reacts with white phosphorus to give X. The reaction of X with pure HNO₃ gives Y and Z.

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Linked Question 1

W and X are, respectively

O₂ and P₄O₁₀

O₃ and P₄O₆

O₃ and P₄O₁₀

O₂ and P₄O₆

${KClO}_{3} \overset{{MnO}_{2}}{\to} KCl + \frac{3}{2} O_{2} [W]$

$P_{4} + \underset{(excess amount)}{O_{2}} \to_{}^{} \underset{[X]}{P_{4} O_{10}}$

$P_{4} O_{10} + {HNO}_{3} \to_{}^{} \underset{[Y]}{N_{2} O_{5}} + \underset{[Z]}{{HPO}_{3}}$

Linked Question 2

Y and Z are, respectively

N₂O₃ and H₃PO₄

N₂O₄ and H₃PO₃

N₂O₄ and HPO₃

N₂O₅ and HPO₃

${KClO}_{3} \overset{{MnO}_{2}}{\to} KCl + \frac{3}{2} O_{2} [W]$

$P_{4} + \underset{(excess amount)}{O_{2}} \to_{}^{} \underset{[X]}{P_{4} O_{10}}$

$P_{4} O_{10} + {HNO}_{3} \to_{}^{} \underset{[Y]}{N_{2} O_{5}} + \underset{[Z]}{{HPO}_{3}}$