Engineering
Chemistry
Adsorption
Gold Number and Flocculation value
Colloids Preparation and Properties
Question

Which of the following are correct statements

A colloid of Fe(OH)3 is prepared by adding a little excess (required to completely precipitate Fe3+ ions as Fe(OH)3)) of NaOH in FeCl3 solution the particles of this sol will more towards cathode during electrophoresis.

According to Hardy-Schulze rules the coagulation (flocculating) value of Fe3+ ion will be more than Ba2+ or Na+.

Formation of micelles takes place when temperature is below Kraft Temperature(Tk) and concentration is above critical micelle concentration (CMC)

Spontaneous adsorption of gases on solid surface is an exothermic process as entropy decreases during adsorption

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Solution
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⇒ ΔG = ΔH – TΔS < O  as ΔS < O so ΔH has to be negative

⇒ micelles formation will take place above Tk and above CMC

⇒ this solution will be negatively charged.

⇒ Fe3+ ions will have greater flocculatibility power so smaller flocculating value.