Engineering
Chemistry
Crystal Field Theory and Valence Bond Theory
Question

Which of the following facts about the complex [Cr(NH3)6] Cl3 is wrong ?

The complex gives white precipitate with silver nitrate solution.

The complex is an outer orbital complex.

The complex involves d2sp3 hybridisation and is octahedral in shape.

The complex is paramagnetic

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Solution

In case of d3 configuration, the number of unpaired electrons remains 3 whether the ligand is strong field or weak field. The hybridisation scheme can be shown as follow :

Hence the complex is inner orbital complex as it involves (n – 1) d orbitals for hybridisation, 3.93=n(n+2); so n = 3 (here n is number of unpaired electron(s)).