Engineering
Chemistry
Gibbs Free Energy Entropy and Spontaneity
Question

Which of the following is correct statement?

During a spontaneous process entropy of system will always increase.

In case of He(g) more heat has to be given as compared to C2H4(g) for same temperature change at constant volume.

Entropy of a closed system must increase in an irreversible adiabatic process.

ΔS is a state function.

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Solution

The correct statement is: ΔS is a state function.

Entropy change (ΔS) depends only on the initial and final states of a system, not the path taken. For any reversible process between two states, ΔS is defined as the integral of dqrev/T.

ΔS=∫12dqrevT

This makes it a state function, unlike heat (q) or work (w), which are path-dependent.

Final Answer: ΔS is a state function.