Which of the following options have elements / ions with same value of spin multiplicity.
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Spin multiplicity is given by 2S+1, where S is total spin quantum number. To have same multiplicity, total unpaired electrons must be equal.
For Cr (atomic number 24): [Ar]4s13d5 → 6 unpaired electrons → S=3 → multiplicity=7
For Mn+1 (atomic number 25): [Ar]3d6 → 4 unpaired electrons → S=2 → multiplicity=5
These values differ (7 vs 5), so they do NOT have same spin multiplicity.
Final Answer: None of the given pairs have the same spin multiplicity.