Engineering
Chemistry
Fajans Rule and Its Application
Hydration and Lattice Energy
Question

Which one of the following alkaline earth metal sulphates has its hydration enthalpy greater than its lattice enthalpy?

CaSO4

BaSO4

SrSO4

BeSO4

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Solution

(D)         Solubility order of sulphates in water BeSO4 > CaSO4 > SrSO4 > BaSO4

BeSO4 has greater hydration enthalpy than its lattice enthalpy

              Because Be2+ ion has maximum charge density.