Engineering
Chemistry
Law of Chemical Equivalence
Titration
Question

15 g Ba(MnO4)2, sample containing inert impurity is completely reacting with 100 mL of 11.2 V H2O2. What will be the % purity of Ba(MnO4)2 in the sample?

5

10

50

None of the above
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Solution

Normality of H2O2=11.25.6N
Milliequivalents Ba(MnO4)2 reacted = milli equivalents of H2O2 reacted = 2 × 100 = 200 meq. = 0.2 gram eq.
Moles of Ba(MnO4)0.210=0.02
 Weight of Ba(MnO4)2 = 0.02 × 375
Percentage purity of Ba(MnO4)2 375×0.0215×100=50%.