A colorless aqueous solution contains nitrates of two metals, X and Y. When it was added to an aqueous solution of NaCl, a white precipitate was formed. This precipitate was found to be partly soluble in hot water to give a residue P and a solution Q. The residue P was soluble in aq. NH3 and also in excess sodium thiosulfate. The hot solution Q gave a yellow precipitate with KI. The metals X and Y, respectively, are
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X : Ag P : AgCl
Y : Pb Q : PbCl2

(P) (excess) clear solution
AgCl + 2Na2S2O3 solution → Na3 [Ag(S2O3)2] + NaCl
(P) (excess) clear solution
PbCl2 + 2KI → PbI2 + 2KCl
Hot solution (yellow ppt)
(Q)